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العنوان
Studies of he stereochemistry and kinetics of addiion of nucleophiles to substituted phenyl propiolate esters /
الناشر
Alexandria University.Faculty of science,
المؤلف
Hamed, Ezzat Awad.
هيئة الاعداد
مشرف / سمير كميل السعدنى
مشرف / سائر محمد شرف
مشرف / عبد الحميد احمد يوسف
باحث / عزت عوض حامد
الموضوع
Physical Chemistry - Science.
تاريخ النشر
1985 .
عدد الصفحات
ix, 268, 5 p. :
اللغة
الإنجليزية
الدرجة
الدكتوراه
التخصص
Organic Chemistry
تاريخ الإجازة
1/1/1985
مكان الإجازة
جامعة الاسكندريه - كلية العلوم - Chemistry
الفهرس
Only 14 pages are availabe for public view

from 422

from 422

Abstract

;a-substi tuted 0( P -dibromoc:tnnamate esters to the corresponding p-sub-
;.t1tuted phenyl propiolic acids. The methyl estLrs ~a-e were
:’prepared by direct treatment of .E.-substituted phenyl propiolic acids ~w1th
absolute methanol and hydrogen chloride.
t,. •
a- The reactions of compounds ~a-e with piperidine, diethyllamine and morpholine
in absolute methanol gave exclusively {!)-methyl
-(N,N-dialkyl)-amino .E.-substituted cinnamates.
b- The reactions of the acetylenic esters ~a-e with the same am1nes in pure DMF
gave the same configuration for the adducts as in
case of absolute methanol. Only ~e (I) isomers.
-
yields a mixture of (Z) and
-
Reaction of ~a-e With Amines in Absolute Methanol.
a- The reactions of the acetylenic compounds 1 with amines
,va-e
.