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Abstract ;a-substi tuted 0( P -dibromoc:tnnamate esters to the corresponding p-sub- ;.t1tuted phenyl propiolic acids. The methyl estLrs ~a-e were :’prepared by direct treatment of .E.-substituted phenyl propiolic acids ~w1th absolute methanol and hydrogen chloride. t,. • a- The reactions of compounds ~a-e with piperidine, diethyllamine and morpholine in absolute methanol gave exclusively {!)-methyl -(N,N-dialkyl)-amino .E.-substituted cinnamates. b- The reactions of the acetylenic esters ~a-e with the same am1nes in pure DMF gave the same configuration for the adducts as in case of absolute methanol. Only ~e (I) isomers. - yields a mixture of (Z) and - Reaction of ~a-e With Amines in Absolute Methanol. a- The reactions of the acetylenic compounds 1 with amines ,va-e . |