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العنوان
Chemical evaluation for water resources and enhancement of drinking water characterestics in dakahlya /
المؤلف
Hammad, Shaimaa Mohamed Mahmoud.
هيئة الاعداد
باحث / شيماء محمد محمود حماد
مشرف / إبراهيم محمد مرسى قناوى
مشرف / على على على سرحان
الموضوع
Chloromethylated Polystyrene.
تاريخ النشر
2010.
عدد الصفحات
137 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
الكيمياء
تاريخ الإجازة
01/01/2010
مكان الإجازة
جامعة المنصورة - كلية العلوم - Department Of Chemistry
الفهرس
Only 14 pages are availabe for public view

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Abstract

Chloromethylated polystyrene polymer (CMPS – polymer) has been modified with1 amino2 naphthol β sulphonic acid sodium salt (ANSA) and Eriochrome cyanine R (ECR) to be used as a new reagent for preconcentration of Cu(II), Co(II), Ni(II), Mn(II), Zn(II), Cd(II), Hg(II), Pb(II), Al(III), Fe(III) and Cr(III) ions. The modified polymers (ANSA-Polymer) and (ECR – polymer) have been characterized by elemental analysis and IR spectra. Batch and column extraction modes were described. Stability and reactivity of the modified resins did not affect by the presence of common organic solvents such as; ethanol, acetone, benzene and carbon tetra chloride . The resin kept its sorption capacity after treatment with 2 moll-1 of electrolytic solutions of KC1, NaCl and NaOH, and more or less unchanged in the presence of 5 moll-1 of acid solution, such as; hydrochloric or nitric acid . The optimum pH for the maximum sorption capacity of all the studied metal ions lie within the range 5 ~8. All the metal ions sorbed could be eluted using 0.5 moll-1 hydrochloric acid solution taken the advantage that, chloride ions is an acceptable matrix for both AAS and spectrophotomctric determinations. The complexation between metal ions and organic reagents loaded on CMPS-resin, could be evidenced by themal analysis,IR spectra and potentiometric titration. The proposed modified resins were applied for separation and preconcentration of metal ions from: Water samples ( Nile and Tap water).