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العنوان
Studies on the inhibiting action of some 4­ antipyrine derivatives on the corrosion of zinc in aqueous solutions /
المؤلف
Ahmed, Ahmed Mohammed El­-Desoky.
هيئة الاعداد
باحث / أحمد محمد الدسوقى أحمد
مشرف / عبدالعزيز السيد فودة
مشرف / مصطفي أمين دياب
مشرف / أحمد أحمد الصروي
الموضوع
Zinc - Corrosion. Solution (Chemistry).
تاريخ النشر
2004.
عدد الصفحات
204 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Physical and Theoretical Chemistry
تاريخ الإجازة
01/01/2004
مكان الإجازة
جامعة المنصورة - كلية العلوم - Department of Chemistry
الفهرس
Only 14 pages are availabe for public view

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Abstract

The aim of the present work,is to study the corrosion and corrosion inhibition of Zinc in hydrochloric acid and sodium hydroxide solutions, and this study is due to the importance of Zinc,inhibition of its corrosion by using organic inhibitors such as 4­antipyrine derivatives. This work is carried out by using two methods:chemical method (weight­loss method) and electrochemical method (galvanostatic polarization method);this enable us to calculate the percentage inhibition of these derivatives and compare between them.Also study the effect of constant concentration from: (i)potassium iodide,thiosycanate,bromide on the inhibition percentage in acidic medium,(ii) barioum chloride,calcium,strentium,magnesium on the inhibition percentage in alkaline medium.The effect of temperature was studied by these two methods;this enable us to calculate activation energy, other parameters and type of adsorption on Zinc surface(physical or chemical).The electrochemical method enables us to determine the mechanism of the inhibition process(cathodic or anodic).