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العنوان
Effect of electron beam irradiation on the physicochemical properties of some polymeric foam blends /
المؤلف
Eyssa, Hanan Mohamed El-Amine Mohamed El-Mahdy.
هيئة الاعداد
باحث / حنان محمد الأمين محمد المهدى عيسى
مشرف / السيد محمد عبدالبارى
مشرف / حسين عامر على يوسف
مشرف / مجدى محمد حسن سنه
الموضوع
Blends. Polyethylene. Electron beam. Foaming agent. Crosslinking.
تاريخ النشر
2005.
عدد الصفحات
103 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
الكيمياء
تاريخ الإجازة
01/01/2005
مكان الإجازة
جامعة المنصورة - كلية العلوم - Department of Chemistry
الفهرس
Only 14 pages are availabe for public view

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Abstract

In this thesis, low density polyethylene, low density polyethylene<U+2013> poly ( ethylene vinyl acetate )(80/20 ) and low density polyethylene <U+2013> poly (ethylene propylene diene rubber) (80/20) were mixed with polyfunctional monomers namely 1,6 <U+2013> hexandiol diacrylate (2 %) and Azodicarbonamide as foaming agent of different concentrations 0.5, 1, 1.5, 2.5, 5, 7.5 % . The specimens were hot pressed and exposed to electron beam irradiation at different irradiation doses namely 25, 50, 75 and 100 kGy for LDPE and LDPE/EVA and 5, 10, 15 and 20 kGy in case of using LDPE / EPDM . The irradiated samples were subjected to heating up to 225 oC to induce foaming . The effect of irradiation doses and foaming agent concentration on the various properties were followed up . The Rheology measurements reveals that incorporation of EVA in LDPE reduce the melt viscosity of the blend . On the other hand , EPDM increase the melt viscosity . This change was reflected on the low tensile strength of unirradiated and unfoamed LDPE/EVA blend and high tensile values of LDPE/EPDM compared to LDPE . Also , it can be seen that both irradiation dose and foaming agent concentration influence the stress ­ strain curve, in which the stress value increases as irradiation dose increase, whereas, the elongation at rupture decreases .Increasing foaming agent concentration deteriorates both stress and strain for all specimens.