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العنوان
Studies on esterification of some organic acids in presence of ion-exchange resins /
المؤلف
Al-Nahass, Mohamed Radwan.
هيئة الاعداد
باحث / محمد رضوان رضوان النحاس
مشرف / م. نورالدين موسى
مشرف / ي. أ. العوادي
مشرف / أ. م. شلبي
مشرف / أ. م. الوكيل
الموضوع
Esterification. Organic acids. Ion exchange resins.
تاريخ النشر
1982.
عدد الصفحات
112 P. :
اللغة
الإنجليزية
الدرجة
الدكتوراه
التخصص
الكيمياء
تاريخ الإجازة
1/1/1982
مكان الإجازة
جامعة دمياط - كلية العلوم - Department Of Chemistry
الفهرس
Only 14 pages are availabe for public view

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Abstract

The catalyst used in this study of the esterification is a hydrogen from of a cation exchanger of the type Amberlite IR-120 with a capacity of 6.84 meq./gm of a completely anhydrous resin. The effect of the structure of organic acids and the aliphatic alcohol on the esterification rate was investigated using Taft’s equation. A kinetic expression was proposed, to determine the reaction velocity constant k1, and the esterification of formic, acetic, propionic, butyric and valeric acids with a homologous series of alcohols (methanol, ethanol, propanol and butanol) was found to be a second order bimolecular reversible reaction.