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العنوان
Electropolishing of Steel in Presence of Organic Compounds =
المؤلف
Khalil, Ahmed Salah Ali.
هيئة الاعداد
باحث / Ahmed Salah Ali Khalil
مشرف / Prof. Dr. Abdel Monem M. Ahmed
مشرف / Prof. Dr. Hassan Mohamed Mokhtar
مشرف / Prof.Mohamed Abd Elmotalib Elmorsi
الموضوع
Electropolishing. Organic Compounds.
تاريخ النشر
2015.
عدد الصفحات
128 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
الكيمياء
تاريخ الإجازة
13/11/2015
مكان الإجازة
جامعة الاسكندريه - كلية العلوم - Chemistry
الفهرس
Only 14 pages are availabe for public view

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Abstract

The values of thermodynamics parameters ΔH* (kJmol-1), ΔS* (J.mol-1 k-1) and ΔG kJmol-1) are represented. The results show positive sign for ΔH*, reflecting the endothermic nature of the adsorption process. The negative values of ΔS* pointed to greater order produced during the process of activation indicating more ordered and nor random distribution of ions. ΔG* values show limited increase with rise in the concentration of organic additives i.e.: ΔG* values of inhibited systems were more positive than that for the uninhibited systems. The isokinetic temperature β were estimate, their values are much higher than that of the experimental temperature 298K indicating that the rate of the reaction is enthalpy controlled, if their values are lower than 298 K indicating that the rate of the reaction is entropy controlled.