Search In this Thesis
   Search In this Thesis  
العنوان
Development of the electrodeposited platinum and its alloys as catalysts for direct methanol fuel cell (DMFC) /
المؤلف
Saber,Mansour Sadek Ibrahim.
هيئة الاعداد
مشرف / حسنية صابر مهران
مشرف / هاني محمد عبد اللطيف
مشرف / محمود الروبي محمد محمود
مناقش / محمود خضاري
باحث / منصور صادق ابراهيم
الموضوع
methanol fuel cell.
تاريخ النشر
2019.
عدد الصفحات
p 204. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Physical and Theoretical Chemistry
تاريخ الإجازة
27/5/2019
مكان الإجازة
جامعة سوهاج - كلية العلوم - كيمياء
الفهرس
Only 14 pages are availabe for public view

from 280

from 280

Abstract

A novel composite catalysts of Pt nanorods and nanostructure<>PtCo, PtNi and PtMo alloys onto a glassy carbon electrode (GCE)
modified with nanostructured NiCo alloy are successfully electrosynthesized
for the electrocatalytic oxidation of methanol. The
morphology, chemical composition, and phase structure for the
electrodeposited catalysts are examined using scanning electron
microscope (SEM), energy dispersive X-ray spectroscopy (EDX),
and X-ray diffraction (XRD), respectively. The electrocatalytic
properties of the catalysts are investigated by cyclic voltammetric
(CV) and current-time methods. It is discovered that the
electrodeposited nano flowered NiCo alloy substrate has a great
effect on the electrocatalytic properties of the electrodeposited
catalysts. The effect of electrodeposition time for NiCo alloy is
studied. Also, the effects of the type of electrodeposition method,
pH, temperature, and concentration for the electrodeposition bath
for Pt, PtCo, PtNi and PtMo alloys on the electrocatalytic properties
of the catalysts are well studied. Furthermore, the effect of
temperature and concentration of methanol solution on MOR are