الفهرس | Only 14 pages are availabe for public view |
Abstract Blended cement are made by the partial replacement of ordinary Portland cement by siliceous materials such as silica fume, blast furnace slag and CKD such blending materials modify the strength, pore structure and permeability of the hardened cement pastes. Sulphate attack on hardened cement pastes causes a serious deterioration. The damage usually starts at edges and followed by cracking of cubes. Magnesium sulphate has a more damage effect than other sulphates because it leads to the decomposition of the hydrated calcium silicate as and hydrated calcium aluminates. Therefore, the aim of this investigation is to study the physicochemical and mechanical properties of some hardened blended cement pastes by examining the hydration characteristics of various mixes as well as magnesium sulphate attack. The effect of the additives such as silica fume, blast furnace slag and CKD was examined. Different mixes were prepared with various ratios of additives and cured in water for various times (1-7-28-180-360 days) of hydration. After 28 days half of the cubes are immersed in 5% MgSO4 solution to investigate the physicochemical and mechanical properties. SUMMARY 401 The results obtained from the present investigation can be summarized as following:- - All the hardened cement pastes showed an increase in chemically combined water content by increasing the hydration age. This indicates that hydration reaction increase with age of hydration. - The hardened cement pastes blended with CKD, SF, and slag showed an increase in compressive strength than the net Portland cement (OPC) and it also depend on the ratio of this additive. -The increase in compressive strength is due to the continues hydration reaction of anhydrated cement components to form more hydration products in addition to the reaction of SF, and slag with the liberated CH to form more CSH leading to increase compressive strength. - The X-ray diffraction patterns of some representative hardened cement pastes cured in water and in magnesium sulphate solution for various time intervals are studied. SUMMARY 401 - The main hydration products formed by hydration of cement paste (OPC) and blended cement pastes are calcium silicate hydrates (CSH) and calcium hydroxide (CH) in addition to the peaks characteristic of ettringite are seen in the hardened cubes immersed in 5% MgSO4 solution. The optimum amount of silica fume, slag and CKD that give the improvement of hydration characteristics is 20 % for SF, 25 % for slag, 5% CKD and 50 % OPC. The highest compressive strength values are obtained with mixes containing 30 % slag + 20 % silica fume + 40 % OPC +10 % CKD and 25 % slag + 5 % CKD + 20 % silica fume + 50 % OPC |