الفهرس 
LITERATURE SURVEYOnly 14 pages are availabe for public view
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Abstract
The complexes of Sm(III) and Tb(III) with 2-
aminobenzate (anthranilate ion, AA-) and 2-amino-5-chlorobenzate
(5-chloroanthranilate ion, AACl-) were synthesized and
characterized based on elemental analysis, IR and mass
spectroscopy. The data are in accordance with 1:3 [Metal] :
[Ligand] ratio. On the basis of the IR analysis, it was found that the
metals were coordinated to bidentate AA- via the ionized oxygen of
the carboxylate group and to the nitrogen of amino group. While in
5-chloroanthranilate complexes, the metals were coordinated
oxidatively to the bidentate carboxylate group without bonding to
amino group; accordingly, a chlorine affected coordination and
reactivity-diversity was emphasized. Thermal analyses(TGA) and
biological activity of the complexes were also investigated. Density
Functional Theory (DFT) calculations at the B3LYP/6-311++G (d,
p)_ level of theory have been carried out to investigate the
equilibrium geometry of the ligand. The optimized geometry
parameters of the complexes were evaluated using SDDALL basis
set. Moreover, total energy, energy of HOMO and LUMO and
Mullikan atomic charges were calculated. In addition, dipole
moment and orientation have been performed and discussed.