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العنوان
Synthesis, characterization and Evaluation of some Modified Chitosan Resins for Removal of some Heavy Metals from Industrial Wastewater /
المؤلف
Abbas, Mahmoud Bekhit Mohamed.
هيئة الاعداد
باحث / محمود بخيت محمد عباس
مشرف / أ.د/ رجاء الشيخ شھيب
مشرف / أ.د/ أحمد فؤاد محمد الفرارجى
مشرف / أ.د / نبيل عبد المنعم نجم
مناقش / أ.د/ رجاء الشيخ شھيب
الموضوع
Evaluation - Periodicals. Industrial water supply.
تاريخ النشر
2013.
عدد الصفحات
130 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Analytical Chemistry
تاريخ الإجازة
1/1/2013
مكان الإجازة
جامعة الزقازيق - كلية العلوم - الكيمياء
الفهرس
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Abstract

In this study, chitosan was produced and characterized using 1H-NMR, IR, DSC and TGA analyses. The produced chitosan was chemically modified by reaction with glycine and chloroacetic acid. Its adsorption capacity for Cu(II) and Co(II) ions from prepared wastewater was determined and compared to the virgin chitosan. The chemical structures of the prepared biosorbents were confirmed by FTIR, 1H–NMR. The adsorption efficiency of the two biosorbents in neutral (pH = 7) and alkaline medium (pH =9) at 25 oC were determined using atomic absorption spectroscopy (AAS) and thermo-gravimetric analysis (TGA). The two biosorbents show lower adsorption efficiency towards copper and cobalt ions compared to the virgin biosorbent (pure chitosan). Furthermore, the adsorption capacity of glycine–chitosan was higher than the chloroacetic acid–chitosan biosorbents, which attributed to the chelating effect of the amino groups than the chloro–substituted polymer