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Abstract Solar cells have poor spectral response (SR) to short-wavelength light and the sub-band-gap photons (IR) can’t be absorbed inside the solar cell and therefore can’t contribute to the generation of electron—hole pairs. The application of a luminescent down-shifting (LDS) layer has been proposed as a method for improving the poor spectral response (SR) of solar cells to short-wavelengths light. The LDS layer absorbs photons, typically in the 300—500 nm range, and re-emits them at a longer wavelength where the photovoltaic (PV) device exhibits a significantly better response. The up-conversion luminescent layer has been proposed as a method to partially convert the sub-band-gap photons (IR) to higher photon energies. The up converted photons can then be absorbed inside the solar cell and therefore contribute to the generation of additional electron—hole pairs, potentially leading to significantly higher conversion solar cell efficiencies. This work aiming to prepare a thin film layer containing both down shifting active centers and up converter active centers DUCL (Down and Up Conversion Layer) then deposit this film over the surface of the solar cell to enhance its efficiency. CdS was chosen as fluorescence material for the down shifting conversion and Er3~ was chosen as an active centre for the up conversion. CdS and Er3~ ions are embedded in silica (host material) using sol gel technique. The present work contains four main chapters in addition to lists of figures, tables and references. |