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Abstract A Folysaccharide wa.s obtained in 4 - 45 % yield from the ground seeds of Lupinus termis (Variety Giza 2). Its specific optical rota.tional in alka~i .(Ca. + 75) while in cuprammoniumcomplex (Ca. -468.75) Qualitative and quantitative analysis of the polysaccharide hydrolysate Jields four simple sugars : D-galactose. L-arabinose, D-xylose. and L-rhamnose with molecula.’ ra·,.io~ 5 :) : 1 : 1 respectively. The absorption spectrum of the polysaccharide showedthat the linkage between the units were of the B type. The polysaccharide was completely methylated using dimethylsulfoxide as a solvent, dimethyl sulphate and sodium hydroxide. Separation and examination of the fission products of the methylated polysaccharide using thin lJqer chromatograPhic technique and microanalytical, physical measurements showed the presence of 2,3, 6 tri~ethyl-~alactapyranose (0.26 mole), 2,4 di-D=methyl-D-galactopyranose (0.06 mole), 2, J di.-Q-methyl-I-arabinofouranose ’0.21 mole)J 2,3 d1~tlJl’l-D-xylopyranose’ (0.07 mole), 2,J,4·tr1-o-metbr~rhemnOPyraD08e (0.06 mo~e). The main chain of the polysaccharide is found of galactopyranose units linked through linkages and the average ohain length is 26 units of Anhydro-galactopyranose units. A branch occurs at every 5 un1ts. The xylose .and Arabinose un1ts form the branches which are term:i.mtted by rhamnose units. |