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العنوان
Application of sol-Gel technique in radwaste fixation/
الناشر
Elham Hussein Wahby El-Hakim,
المؤلف
El-Hakim, Elham Hussein Wahby.
هيئة الاعداد
باحث / Elham Hussein Wahby El-Hakim
مشرف / H.A. Farag
مشرف / F. Naser Zein
مشرف / A. Abd El-Halim
مشرف / I.D.Abd El-Razik
الموضوع
Radwaste fixation.
تاريخ النشر
1992 .
عدد الصفحات
94 p.:
اللغة
الإنجليزية
الدرجة
الدكتوراه
التخصص
الهندسة
تاريخ الإجازة
1/1/1992
مكان الإجازة
جامعة الاسكندريه - كلية الهندسة - Chemical Engineering
الفهرس
Only 14 pages are availabe for public view

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from 114

Abstract

I hydrogel in spite of its relatively NP02+ can be fixed in Al(011)3 hydroge
Solubility in neutral to slightly alkaline solutions. The loss of Np due to washing the Np-Containing gel with water is below 2%.This loss is
I
dy caused by fine gel fragments suspended in and discharged with
primarl fin
wash water. The amount of genuinely dissolved Np(V) is approximately one order of magnitude lower than that present in the Suspended gel particles. ’Pie low concentration compared to that expected according to the solubility product is caused by strong adsorptive properties of the Al(OH)3 hydrogel. This has been proved both by leaching and loading tests. However, adsorption was found to be weaker in strong ammonia solutions than in weak ones. The adsorption mechanism is discussed. It is assumed that NpO,’ is attached to hydroxyl ions which on their part are bound to the gel.
Dissolution of NP020H in both NHOH and NaOH Solutions was investigated mainly in a CO,-free atmosphere. Results show that solubility of NP0201-1 in NH4011 solution increases with the increase of N1-140H concentration . Absorption spectra of Np(V) in NH.,OH solution shows a characteristic absorption peak at 1002 nm, suggesting its presence as ammino complex having the formula NP020H(NHA, (H20)y